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- Refrigerant Basics and System Maintenance
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View ProductsNever top off a system using one refrigerant with a different replacement refrigerant, as mixing refrigerants is not recommended. The original refrigerant should be recovered using appropriate equipment and managed according to U.S. EPA guidelines specified in Section 608 of the U.S.Clean Air Act. If the two refrigerants have different safety classifications, new safety hazards could also be introduced.
Non-flammable blends commonly used in the industry have flammable components for example R-410A, MO99 (R-438A), R-407A, NU22B (R-422B), but are designated as non-flammable (Class 1) by ASHRAE.
UN/ASHRAE: Update on New Refrigerants Designations and Safety Classifications
Even refrigerants with the same "R-number" from various suppliers may not be of the same quality. Random testing of refrigerants from various suppliers has shown that commercially available products do not always meet AHRI purity, composition, moisture or air standards. Always purchase refrigerants from a trusted and proven supplier.
Many HFOs and HFO blends have been used extensively for both system retrofit and/or new equipment. The determining factor on whether or not a refrigerant can be used in existing systems vs. only new equipment is based on the safety designation. There are several HFOs and/or HFO blends with an ASRHAE Class 1 (non-flammable) designation, which have been used successfully in field retrofits as well as new equipment.
While pure HFCs like R-407C require a full oil change from mineral oil to POE when converting away from R-22, "mineral oil compatible" replacements have been successfully used for decades. Hundreds of thousands of R-22 air conditioning systems have been successfully retrofitted to Freon™ MO99 (R-438A) and Freon™ Nu-22B (R-422B) while continuing to run on mineral oil.
To understand and compare the efficiencies of a new HVACR system, you need to consider the design, components, refrigerant used and the operating conditions. No one factor will determine the energy consumption. When retrofitting systems and only changing refrigerant fluids, it can be reasonable to compare performance on the basis of the refrigerant properties themselves. However, when comparing different fluids that will be used in distinct system designs and/or under different operating conditions, this comparison becomes less consequential. Whether talking about cooling capacity, energy efficiency ratings, or environmental impact, the total system footprint determines the outcome. "Selection of refrigerants and their systems must be based on a holistic analysis including energy efficiency and performance attributes, environmental impacts, employee and public safety, and economic considerations. A refrigerant should not be selected based on any one single factor such as GWP, operating pressure, flammability, etc."
Every equipment manufacturer today makes available specifications for the optimal refrigerant charge. Typically, this involves weighing in charge or measuring superheat and/or subcooling values. Not following the manufacturer's guidelines could lead to a reduction in performance or an increase in callbacks.
https://www.achrnews.com/articles/141371-five-rules-for-charging-refrigeration-systems
R-22 replacements like any product will have a prescribed set of guidelines that technicians must follow. These guidelines are also accompanied by a list or applications or units that the product cannot be used in. When comparing options, there are several points technicians should be aware of such as need for oil change out and replacing critical elastomeric seals.
https://www.freon.com/en/-/media/files/freon/freon-mo99-retrofit-guidelines.pdf
The same best practices and tools used to recover A1 refrigerants such as R-410A and R-404A are used to recover next generation A2L refrigerants such as XL41 (R-454B) and XL20 (R-454C). Technicians should take special consideration to check that their tools, such as vacuum pumps, recovery machines, and recovery tanks are approved for use with products that carry the A2L safety designation. Several manufacturers have already approved models for use, have you checked what’s on your truck?
The Kigali Amendment and associated regulations (AIM Act, F-Gas, ODSHAR) specify a phasedown of HFCs based on CO₂ equivalents. Not a phaseout or manufacturing ban.
https://hvacr.elearn.network/courses/phase-down-vs-phase-out-what-s-the-difference
https://www.epa.gov/system/files/documents/2021-09/hfc-allocation-rule-nprm-fact-sheet-finalrule.pdf
CO₂ systems require components that operate at much higher working pressures, or utilize costly mitigation tactics for high ambient operation.
https://www.coolingpost.com/features-home/heatwaves-and-co2-refrigeration/